Jamie Curtis has joined the lender to support brokers in the Thames Valley region, while Rhiannon Adams will support South West region.
Recruitment on additional new posts is expected to be completed in September, the lender said.
This is part of its corporate account and sales team expansion plans.
Before Leeds Building Society, Helen Cawthra (pictured) worked at Lloyds Banking Group as a business development manager for a decade.
Working alongside Accord’s existing corporate account managers, she will manage relationships and provide support to the provider’s key lending partners.
Jeremy Duncombe, director of intermediary distribution at Accord, said: “We’re delighted to welcome such high quality colleagues to the team as we continue with our ambitious growth plans.
“Helen will work closely with our key lending partners to help us add value to their advisers and members to ensure they’re getting the most from our proposition, including our common sense approach to underwriting and direct access to underwriters.
“Jamie and Rhiannon will work regionally, supporting individual brokers and firms. One of our main objectives is to help brokers give the best possible service to their clients and strengthening our sales team underlines that commitment.”